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991.
L. M. Mironovich 《Chemistry of Heterocyclic Compounds》1994,30(9):1092-1094
3-Hydrazino-6-tert-butyl-1,2,4-triazolo[3,4,c]-1,2,4-triazin-5-one was synthesized by the reaction of a substituted 4-(N,N-dimethylcarbamoyl)-3-thioxo-1,2,4-triazine with hydrazine. The spectral characteristics and the proposed reaction mechanism are discussed.The Sumy State University, Sumy 244007. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1258–1260, September, 1994. Original article submitted September 14, 1994. 相似文献
992.
The interactions of Cu(II) in Cu(II)-exchanged K-L gallosilicate with adsorbates containing coordinative nitrogens in ammonia, pyridine, aniline, acetonitrile and hydrazine, and with the adsorbates carbon monoxide, benzene, propanol and dimethyl sulfoxide are investigated by electron spin resonance (ESR) and electron spin echo modulation (ESEM) spectroscopies. These results are compared with those in Cu(II)-exchanged K-L aluminosilicate and the differences are discussed. Adsorption of ammonia produces a complex containing four molecules of ammonia based on resolved nitrogen superhyperfine interaction. Upon equilibrium with pyridine, Cu(II) forms a complex containing four molecules of pyridine in CuK-L gallosilicate and a complex containing only three molecules of pyridine in CuK-L aluminosilicate based on resolved nitrogen superhyperfine. Upon adsorption of aniline and acetonitrile, Cu(II) forms complexes containing two molecules of each in CuK-L gallosilicate based on resolved nitrogen superhyperfine. However, no resolved nitrogen superhyperfine between hydrazine and Cu(II) is seen. Adsorption of carbon monoxide, benzene, propanol and dimethyl sulfoxide causes changes in the ESR spectrum of Cu(II), indicating migration of Cu(II) into cation positions in the main channels where adsorbate coordination can occur. Cu(II) forms complexes with one molecule of benzene and two molecules of propanol based on ESEM data in both K-L gallosilicate and K-L aluminosilicate. However, Cu(II) interacts directly with one dimethyl sulfoxide in K-L aluminosilicate but only indirectly at a longer distance with one dimethyl sulfoxide in K-L gallosilicate based on ESEM data. 相似文献
993.
Two groups of 10 speech-language pathology graduate students were each given 7 weeks of singing lessons to determine whether voice lessons could have an effect on their clinical and perceptual skills. Pre-, mid-, and posttests to measure various skills were designed and implemented. With use of paired sample statistical testing, statistically significant results were obtained. In addition, the subjective responses of the students show that the lessons were effective in improving pitch perception, breath control, and legato production or easy onset. This study supports efforts to integrate curricula in vocal performance and speech-language pathology. 相似文献
994.
Flowing and static gas-phase samples of HNO3 in O2 and N2 were analyzed by long-path ultraviolet/visible (UV/VIS) spectroscopy to reveal the presence of both NO2 and NO3, the concentrations of which were calculated using differential absorption cross sections. NO2 is produced predominantly by the heterogeneous decomposition of HNO3, whereas NO3 is generated in the gas phase by the thermal decomposition of N2O5, a product of the self-disproportionation of liquid HNO3. © 1993 John Wiley & Sons, Inc. 相似文献
995.
996.
V. P. Burskii 《Ukrainian Mathematical Journal》1993,45(11):1659-1668
Elliptic systems of two second-order equations, which can be written as a single equation with complex coefficients and a homogeneous operator, are studied. The necessary and sufficient conditions for the connection of traces of a solution are obtained for an arbitrary bounded domain with a smooth boundary. These conditions are formulated in the form of a certain moment problem on the boundary of a domain; they are applied to the study of boundary-value problems. In particular, it is shown that the Dirichlet problem and the Neumann problem are solvable only together. In the case where the domain is a disk, the indicated moment problem is solved together with the Dirichlet problem and the Neumann problem. The third boundary-value problem in a disk is also investigated.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 45, No. 11, pp. 1476–1483, November, 1993. 相似文献
997.
998.
Summary. We study a diffusion model of an interacting particles system with general drift and diffusion coefficients, and electrostatic
inter-particles repulsion. More precisely, the finite particle system is shown to be well defined thanks to recent results
on multivalued stochastic differential equations (see [2]), and then we consider the behaviour of this system when the number
of particles goes to infinity (through the empirical measure process). In the particular case of affine drift and constant diffusion coefficient,
we prove that a limiting measure-valued process exists and is the unique solution of a deterministic PDE. Our treatment of
the convergence problem (as ) is partly similar to that of T. Chan [3] and L.C.G. Rogers - Z. Shi [5], except we consider here a more general case allowing
collisions between particles, which leads to a second-order limiting PDE.
Received: 5 August 1996 / In revised form: 17 October 1996 相似文献
999.
The effect of 57Fe hyperfine interaction radiofrequency (rf) modulation by external rotating magnetic field was studied in thin Permalloy foil by means of Mössbauer spectroscopy. The rf effect was investigated as a function of intensity for several rf field frequencies. The experiments show that the external rotating rf field causes considerable changes in the hyperfine pattern. The obtained spectra are in disagreement with those obtained by Perlow [Phys. Rev. 172 (1968) 319]. They also are inconsistent with magnetostriction hypothesis. Proceeding from the Mössbauer spectrum analysis one may conclude that the magnetization of investigated foil changes its direction in a complex manner. However, the undertaken experiments show that the essential number of Mössbauer nuclei experience the rotating magnetic field influence. 相似文献
1000.
A theoretical model of Dewangan, in which the total scattering wave function is approximated by a distorted wave containing
two Coulomb wave functions, is discussed and its relation with the Brauner-Briggs-Klar model for ionization is examined. An
important feature of the theory is that it includes a second Born amplitude naturally and in addition, contains, albeit approximately,
both real and imaginary parts of all higher order Born terms. The theory is applied to study the 1s→2s excitation of hydrogen by electrons in the energy range 54.4 to 400eV. The differential and integral cross sections predicted
by the theory are compared with the results of other theories and experimental data at 54.4eV and a good agreement is found. 相似文献